Assessment of Boron-Modified Semicarbazide and Thiosemicarbazide Resins as Corrosion Inhibitors for Carbon Steel Alloy in Acidic Environment
DOI:
https://doi.org/10.54153/sjpas.2025.v7i1.854Keywords:
Semicarbazide-Formaldehyde, Thiosemicarbazide-Formaldehyde, Boric acid, Corrosion Inhibitors, ResinsAbstract
This study aims to synthesize two types of resins derived from semicarbazide and thiosemicarbazide for use as corrosion inhibitors. boron-Modified semicarbazide-formaldehyde resin (SFB) derived from semicarbazide, formaldehyde, and boric acid, and the other inhibitor boron-Modified thiosemicarbazide-formaldehyde resin (TSFB) derived from thiosemicarbazide, formaldehyde, and boric acid, they were studied using FTIR and TGA techniques. They were evaluated as inhibitors of corrosion of carbon steel alloy in a corrosive acidic environment of 0.1 M hydrochloric acid at several temperatures (25, 35, 45, 55) °C and at different concentrations for both inhibitors separately, using the Tafel extrapolation method. Where (SFB) gave the best inhibition efficiency at a concentration of 4 ppm, whereas the best inhibition efficiency was For (TSFB) at a concentration of 10 ppm. The investigation focused on activation parameters like E_a, 〖∆H〗^* and 〖∆S〗^*. It was observed that the activation energy was higher when an inhibitor was present than when it was absent. Additionally, the research revealed that the corrosion reaction is exothermic. The activation entropy demonstrated an increase in the number of corrosive species at elevated temperatures, which is attributed to the increased kinetic energy of these species as they interact with the alloy surface.
References
1. Vasechkina, I. A., Gladchenkova, Y. S., & Amezhnov, A. V. (2023). Effect of pipe steel chemical composition and structural characteristics on corrosion resistance under Western Siberia oilfield pipeline operating conditions. Metallurgist, 67(5–6), 579–589. https://doi.org/10.1007/s11015-023-01546-9
2. Natarajan, K. A. (2020). Principles of Corrosion Processes. Structural Integrity, 27–82. https://doi.org/10.1007/978-3-030-32831-3_2
3. Jellesen, M. S. (2018). Metals and corrosion. Metal Allergy, 17–22. https://doi.org/10.1007/978-3-319-58503-1_2
4. Ma, I. A., Ammar, Sh., Kumar, S. S., Ramesh, K., & Ramesh, S. (2021). A concise review on corrosion inhibitors: Types, mechanisms and electrochemical evaluation studies. Journal of Coatings Technology and Research, 19(1), 241–268. https://doi.org/10.1007/s11998-021-00547-0
5. Ahmed, S. K., Ali, W. B., & Khadom, A. A. (2019). Synthesis and investigations of heterocyclic compounds as corrosion inhibitors for mild steel in hydrochloric acid. International Journal of Industrial Chemistry, 10(2), 159–173. https://doi.org/10.1007/s40090-019-0181-8
6. Ates, M. (2016). A review on conducting polymer coatings for corrosion protection. Journal of Adhesion Science and Technology, 30(14), 1510–1536. https://doi.org/10.1080/01694243.2016.1150662
7. Xu, H., & Zhang, Y. (2019). A review on conducting polymers and nanopolymer composite coatings for steel corrosion protection. Coatings, 9(12), 807. https://doi.org/10.3390/coatings9120807
8. Ide, Y., Manabe, Y., Inaba, Y., Kinoshita, Y., Pirillo, J., Hijikata, Y., Yoneda, T., Shivakumar, K. I., Tanaka, S., Asakawa, H., & Inokuma, Y. (2022). Determination of the critical chain length for macromolecular crystallization using structurally flexible polyketones. Chemical Science, 13(34), 9848–9854. https://doi.org/10.1039/d2sc03083g
9. Tiu, B. D., & Advincula, R. C. (2015). Polymeric corrosion inhibitors for the oil and gas industry: Design principles and mechanism. Reactive and Functional Polymers, 95, 25–45. https://doi.org/10.1016/j.reactfunctpolym.2015.08.006
10. Fekry, A. M., & Mohamed, R. R. (2010). Acetyl thiourea chitosan as an eco-friendly inhibitor for mild steel in sulphuric acid medium. Electrochimica Acta, 55(6), 1933–1939. https://doi.org/10.1016/j.electacta.2009.11.011
11. Gharbi, O., Thomas, S., Smith, C., & Birbilis, N. (2018). Chromate replacement: What does the future hold? Npj Materials Degradation, 2(1). https://doi.org/10.1038/s41529-018-0034-5
12. Serdaroğlu, G., & Kaya, S. (2021). Organic and inorganic corrosion inhibitors. Organic Corrosion Inhibitors, 59–73. https://doi.org/10.1002/9781119794516.ch4
13. Tang, Z. (2019). A review of corrosion inhibitors for rust preventative fluids. Current Opinion in Solid State and Materials Science, 23(4), 100759. https://doi.org/10.1016/j.cossms.2019.06.003
14. Ress, J., Martin, U., & Bastidas, D. M. (2021). Improved corrosion protection of acrylic waterborne coating by doping with microencapsulated corrosion inhibitors. Coatings, 11(9), 1134. https://doi.org/10.3390/coatings11091134
15. Moses, Joseph & Chinweike, Ekenyem & Imah, Adindu. (2019). Evaluating the inhibitive synergy of di-anodic inhibitors in abatement of low carbon steel corrosion in cooling water systems. 4. 67-72. https://doi.org/10.36713/epra2016
16. Yi, X., Feng, A., Shao, W., & Xiao, Z. (2015). Synthesis and properties of graphene oxide–boron-modified phenolic resin composites. High Performance Polymers, 28(5), 505–517. https://doi.org/10.1177/0954008315587953
17. Patel, K. D., Desai, D. J., Morekar, M. M., & Tilak, Y. S. (2004). Synthesis, characterization and glass - reinforced composites of thiourea - formaldehyde - phenol resin. E-Journal of Chemistry, 1(5), 256–262. https://doi.org/10.1155/2004/569824
18. Nagieb, Z. A., Nassar, M. A., & El-Meligy, M. G. (2011). Effect of addition of boric acid and borax on fire-retardant and mechanical properties of urea formaldehyde saw Dust Composites. International Journal of Carbohydrate Chemistry, 2011, 1–6. https://doi.org/10.1155/2011/146763
19. Xiong, Y., Wan, L., Xuan, J., Wang, Y., Xing, Z., Shan, W., & Lou, Z. (2016). Selective recovery of ag(i) coordination anion from simulate nickel electrolyte using corn stalk based adsorbent modified by ammonia–thiosemicarbazide. Journal of Hazardous Materials, 301, 277–285. https://doi.org/10.1016/j.jhazmat.2015.09.003
20. Yi, X., Feng, A., Shao, W., & Xiao, Z. (2015). Synthesis and properties of graphene oxide–boron-modified phenolic resin composites. High Performance Polymers, 28(5), 505–517. https://doi.org/10.1177/0954008315587953
21. Zhang, L., Ni, C., Zhu, C., Jiang, X., Liu, Y., & Huang, B. (2009). Preparation and adsorption properties of chelating resins from thiosemicarbazide and formaldehyde. Journal of Applied Polymer Science, 112(4), 2455–2461. https://doi.org/10.1002/app.29627
22. Gao, J., Liu, Y., & Yang, L. (1999). Thermal stability of boron-containing phenol formaldehyde resin. Polymer Degradation and Stability, 63(1), 19–22. https://doi.org/10.1016/s0141-3910(98)00056-1
23. Alasadi, Alhawraa & Al-Sawaad, Hadi & Alwaaly, Ahmed. (2023). Synthesis, Characterization and evaluation of two organic compounds as corrosion inhibitors for carbon steel alloy (C1010) in acidic medium of 0.1M HCl. Journal of Kufa for Chemical Sciences. 2. 143-162. http://dx.doi.org/10.36329/jkcm/2022/v2.i9.13292
24. Zhang, F., Deng, S., Wei, G., & Li, X. (2023). Alternanthera philoxeroides extract as a corrosion inhibitor for steel in CL3CCOOH solution. International Journal of Electrochemical Science, 18(3), 100057. https://doi.org/10.1016/j.ijoes.2023.100057
25. Mustafa, F. A., Al-Sawaad, H. Z., & Saki, T. A. (2024). Evaluation of boron-modified guanidine resin as corrosion inhibitors for carbon steel alloy against acidic medium of hydrochloric acid. Mor. J. Chem., 12(2), 614-626. https://doi.org/10.48317/IMIST.PRSM/morjchem-v12i2.45805
26. Wang, L., Zheng, H., Zi, X.-M., Zhang, S.-W., Peng, L., & Xiong, J. (2016). Evaluation of inhibition efficiency of 1-(2-pyridylazo) -2-naphthol and bromide ion on the corrosion of mild steel in sulphuric acid solution. International Journal of Electrochemical Science, 11(8), 6609–6626. https://doi.org/10.20964/2016.08.17
27. Pushpanjali, Rao, S. A., & Rao, P. (2017). Corrosion inhibition and adsorption behavior of Murraya koenigii extract for corrosion control of aluminum in hydrochloric acid medium. Surface Engineering and Applied Electrochemistry, 53(5), 475–485. https://doi.org/10.3103/s1068375517050088
28. Sanumi O. J., Saliu O. D., & Makhatha M. E. (2021). Alternative surface localization studies and electrochemical investigation of tyrosine hybridized poly (ethylene glycol) for corrosion inhibition of mild steel. Journal of Materials Research and Technology, 13, 700–715. https://doi.org/10.1016/j.jmrt.2021.05.007
29. Shivakumar S. S., & Mohana K. N. (2013). Corrosion behavior and adsorption thermodynamics of some Schiff bases on mild steel corrosion in Industrial Water Medium. International Journal of Corrosion, 2013, 1–13. https://doi.org/10.1155/2013/543204
30. Moustafa A. H., Abdel-Rahman H. H., Mabrouk D. F., & Omar A. Z. (2022). Mass transfer role in electropolishing of Carbone steel in H3PO4 containing amino acids: Electrochemical, computational, SEM/EDX, and Stylus Profilometer investigation. Alexandria Engineering Journal, 61(8), 6305–6327. https://doi.org/10.1016/j.aej.2021.11.062
31. Chaouiki A., Chafiq M., Lgaz H., Al-Hadeethi M. R., Ali I. H., Masroor S., & Chung I.-M. (2020). Green corrosion inhibition of mild steel by hydrazone derivatives in 1.0 M HCl. Coatings, 10(7), 640. https://doi.org/10.3390/coatings10070640
32. Okewale A. O., & Adesina O. A. (2020). Kinetics and thermodynamic study of corrosion inhibition of mild steel in 1.5m hcl medium using cocoa leaf extract as inhibitor. Journal of Applied Sciences and Environmental Management, 24(1), 37. https://doi.org/10.4314/jasem.v24i1.6
33. Manssouri M., Znini M., Lakbaibi Z., Ansari A., & El Ouadi Y. (2020). Experimental and computational studies of perillaldehyde isolated from Ammodaucus leucotrichus essential oil as a green corrosion inhibitor for mild steel in 1.0 M HCL. Chemical Papers, 75(3), 1103–1114. https://doi.org/10.1007/s11696-020-01353-5
34. Dalhatu S. N., Modu K. A., Mahmoud A. A., Zango Z. U., Umar A. B., Usman F., Dennis J. O., Alsadig A., Ibnaouf K. H., & Aldaghri O. A. (2023). L-arginine grafted chitosan as corrosion inhibitor for mild steel protection. Polymers, 15(2), 398. https://doi.org/10.3390/polym15020398
35. Zhang Y., Zhang S., Tan B., Guo L., & Li H. (2021). Solvothermal synthesis of functionalized carbon dots from amino acid as an eco-friendly corrosion inhibitor for copper in sulfuric acid solution. Journal of Colloid and Interface Science, 604, 1–14. https://doi.org/10.1016/j.jcis.2021.07.034
36. Yun J., Chen L., Zhao H., Zhang X., Ye W., & Zhu D. (2018). Boric acid as a coupling agent for preparation of phenolic resin containing boron and silicon with enhanced char yield. Macromolecular Rapid Communications, 40(17). https://doi.org/10.1002/marc.201800702
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